Mdi msds

Page copy protected against web site content

        infringement by Copyscape

Proprietary. MDI may undergo uncontrolled exothermic polymerization upon contact with incompatible materials, especially strong bases, such as triethylamine and sodium hydroxide, trialkyl phosphines, potassium acetate, & many metal compounds soluble in organic media. 005ppm N/E 0. demand for pure MDI was 192. The content of monomeric MDI generally is between 45% and 65% on a w/w basis (Mobay, 1983). com. material safety data sheet date: 2012-1-1 sds no. Hazardous according to criteria 2 Part Polyurethane Compound MDI. The Material Safety Data Sheet (MSDS) for MDI polyol prepolymer  Aug 22, 2018 This product safety summary provides a plain language description of chemical identity, general product overview, applications and uses,  with MDI can play a role in causing isocyanate sensitization and respiratory . (MDI) 101-68-8 1 - 5% 2,4'-Diphenylmethane Diisocyanate (MDI) 5873-54-1 4. The data in  Jan 8, 2019 Note: CAS 101-68-8 is an MDI isomer that is part of CAS 9016-87-9. Call a physician immediately. Polyolmeric MDI, 9016-87-9, <55, Not established, Not established. 0 – 13. 0 – 7. In the United States, MDI is known as the A-Side and the polyol blend is known as the B-Side. Alibaba. Three isomers are common, varying by the positions of the isocyanate groups around the rings: 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI. In air, TDI and MDI have half-lives of less than 1 day (half -life is the amount of time needed for the amount of TDI or MDI in air to be reduced by one-half). Liquid MDI products (including melted pure and modified MDI) are colorless to yellow liquids with a mild odor. com ABSTRACT Polymeric MDI and its variants are commonly used in coating and adhesive applications. MDI Inc. below, along with the relevant parts of this book in which there  Learn more about Methylene Diphenyl Diisocyanate at tosoh. MDI (A-Side or Isocyanate Side) MDI has a potential risk of causing irritation and sensitization through inhalation and skin contact. [Note: A concentration of 10 ppm methylene bisphenyl isocyanate is equivalent to about 100 mg/m 3. Medical Materials. Not available. PDF library. Ingredient Name, CAS Number, %, OSHA PEL, ACGIH TLV. . Appearance: Dark brown liquid. Our rapid-deploying MDI Compact® Sign System sets up in less than 20 seconds to effectively inform, guide and protect motorists and improve the safety of first responders. Read the entire MSDS for a more thorough assessment of the hazard information on this product. 1 million pounds and for polymeric MDI was 1,418 million pounds (ACC, 2009). carbodiimide-modified MDI) and prepolymers in  Mar 1, 1993 Based on the nature of the chemical and the data provided, MDI polyol . (Hoymann et al. Polyurethane Basic Products. 4,4’ Diphenylmethane diisocyanate (MDI) 101-68-8 20-60 YES 0. according to Regulation (EC) No 1907/2006. Methylene diphenyl diisocyanate, most often abbreviated as MDI, is an aromatic diisocyanate. Table 4 shows the raw materials requirements and Table 5 shows the demand for water. 3 Harmful if inhaled or swallowed. MSDS Page 1 inhalation hazard can exist from MDI aerosols or vapors formed during. Our (M)SDS database is an easy to use, do it yourself tool, and best of all it's free, paid for by our Methylene diphenyl diisocyanate, most often abbreviated as MDI, is an aromatic diisocyanate. Other companies are charging thousands of dollars to set up accounts and give you access to their (M)sds online database. This IRIS assessment for Methylene Diphenyl Diisocyanate (monomeric MDI) and polymeric MDI (PMDI) consists of hazard identification and dose-response assessment data and provides support for EPA risk management decisions. Mar 22, 2001 Synonyms: Polymethylene Polyphenylisocyanate; Polymeric Diphenylmethane Diisocyanate; Polymeric MDI or PMDI. 4. Weight %*. General Information: Read the entire MSDS for a more thorough evaluation of the hazards. A Source Book and Practical Guide produced. This reaction accelerates at higher temperatures. Guidelines for Transloading Polymeric Methylene Diphenyl Diisocyanate (pMDI) U. Diphenylmethane-4,4-diisocyanate is a light yellow colored solid. Methylene diphenyl diisocyanate (MDI) in commercial form typically exists as a mixture of 4,4'-MDI (monomer) and certain oligomers of MDI (Encyclopedia of Chemical Technology, 1983). Medical aspects of work with DIPHENYLMETHANE DIISOCYANATE (MDI) Note that the layout and pagination of this pdf file are not identical to those of the printed CICAD First draft prepared by Dr J. Information Contact & Quotes Forms & FAQs Our Company Store Policies MDI and TDI are the largest volume aromatic diisocyanates, are high production volume chemicals, and are predominantly used in the production of polyurethanes. Jan 9, 2018 Methylene diphenyl isocyanate (MDI) is a chemical used primarily to manufacture polyurethane foam used in a variety of products and  Diphenylmethane diisocyanate (MDI) and toluene diisocyanate (TDI) sold under isocyanates derivatives (e. MATERIAL SAFETY DATA SHEET Product Name: Base Seal® (Component ‘A’, Isocyanate) MSDS-A004 Page 5 of 10 (A) Consult your supervisor or S. 3. Mar 26, 2019 4,4' MDI, POLYMERIC MDI, 2,2, 2,4 MDI. 4,4'-Diphenylmethane diisocyanate, MDI, Methylene di-p-phenylene ester of isocyanic acid, Methylene bis(4-phenyl isocyanate) Given the handling and storage difficulties associated with pure 4,4’-MDI, carbodiimide chemistry is often used to modify and stabilize monomeric methylene diphenyl diisoocyanate (MMDI). 30 - 40. Guidance for Working with MDI and Polymeric MDI: Things You Should Know Purpose The Center for the Polyurethanes Industry (CPI), prepared this guidance to provide information about important health and safety considerations when working with MDI or polymeric MDI. inhalation of mdi mists or vapors may cause respiratory irritation, breathlessness, chest discomfort and reduced pulmonary function. Such badges are known as isocyanate detection badges, isocyanate indicator badges or isocyanate monitoring badges. Pure MDI is used in the production of a variety of polyurethane products like elastomers, sealants, adhesives and coatings. Nov 6, 2007 First Aid - Eye Contact. CAS 101-68-8, molar mass 250. It supplements the comprehensive information contained in your supplier’s Methylene diphenyl isocyanate (MDI) is a chemical used primarily to manufacture polyurethane foam used in a variety of products and industrial applications. Remove any contact  SECTION 4 – TOXICOLOGICAL INFORMATION. Other companies exposure to MDI may cause impairment of lung function. data in other sections ofthe MSDS may also be applicable for state requirements. 5736P). Other Long-Term Effects * Methylene Bisphenyl Isocyanate may cause a skin allergy. 0. Sensitized persons should not be exposed to any mixture containing unreacted MDI. EPA Classification of pMDI in Transportation The United States Environmental Protection Agency (EPA) lists pure MDI as a hazardous substance, and DOT regulates the shipment of pure MDI when contained in single packages Monomeric MDI (MMDI) refers to 4,4’- and 2,4’-isomers of methylene diphenyl diisocyanate. 7 average organic function and maximum of 220 cps (25℃) viscosity which is mixed with monomer MDI of 4,4-diphenyl Supplier and Distributor of Acrylics Monomers,Butyl Acrylate, Arpacryl,Green & environmentally Acceptable Products (GEAPS),Monomers for Synthetic Resin,Others,Personal & home care,Phosphonates,Pigments & Additives,Polyurethanes,Recycled Solvents Disposal of Waste MDI. Physical Hazards: Reacts slowly with water to produce carbon dioxide, which may rupture, closed containers. ADIPRENE® RIBBON FLOW® MDI and LF MDI-based systems for single- and multi-pass rotational casting of rollers for paper making, steel formation, glass transport and printing. Polymeric MDI (PMDI), the primary technical/commercial form of MDI, is actually a mixture that contains 25-80% monomeric 4,4'-MDI as well as oligomers Your new online (M)SDS binder is a place for you to store the material safety data sheets you need to deploy. CANCER INFORMATION: In a two-year inhalation study in rats, exposure to polymeric methylene bisphenylisocyanate (MDI) aerosol caused a significant  Jun 20, 2017 COMPOSITION / INFORMATION ON INGREDIENTS. Product Use: Component of a Polyurethane  Methylene diphenyl diisocyanate (MDI) is a light yellow solid and is an aromatic diisocyanate. The mixture is designated as polymeric MDI Other Health hazard Information: Industrial experience has shown no evidence of carcinogenicity of MDI in humans. Get medical attention. Product Safety Data Sheets (SDS) Safety Data Sheets (SDS) Specialty Products, Inc. A hyper-reactive response to even minimal concentrations of MDI may defelop in sensitized persons. Diisocyanates are manufactured for the production of polyurethanes, a class of polymers. If in a solution it may or may not burn depending on the nature of the material and/or the solvent. S. 5119 POLYMERIC MDI (pMDI) . g. 26447-40-5. Looking for MSDS information regarding the chemicals in a commercial product or a material safety data sheet (MSDS)? Here is THE most complete MSDS list on the Internet, and it's free! By federal law, manufacturers must supply this info in an MSDS which we provide here, FREE! MDI Products the Leader of Non-Stick Technology 3M™ ESPE™ SECURE™ MDI HARD PICK-UP ADHESIVE MSDS SDS binder is a place for you to store the material safety data sheets you need to deploy. As used herein, the terms SDS and MSDS (i. 7. May cause an  safety data sheet (MSDS) is used. METHYLENE BISPHENOL ISOCYANATE (MDI) (CAS 101-68-8). Polymeric MDA: typical constituents Thank You for Visiting Our Website You are exiting the Department of Labor's Web server. First Aid Measures Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. A wide variety of mdi diphenylmethane diisocyanate options are available to you, such as synthetic fibers, syntheses material intermediates, and synthetic rubbers. Use: Di-/polyisocyanate components for the production of polyurethanes. Compare Products: Select up to 4 products. Center Store: Grocery. Liquid at room temperature. Jul 31, 2017 4,4'-methylenediphenyl diisocyanate (MDI) has not been . • TDI and MDI are extremely reactive chemicals and are not likely to stay in the environment. 메틸렌 디페닐 디이소시아네이트는 크게 MDI 단량체와 Polymeric MDI로 구분되는데, MDI 단량체는 2,2’-MDI, 2,4’-MDI, 4,4’-MDI 세 가지 이성질체로 구성되어 있다. Many isocyanate producers recommend that employees with exposure potential should wear TDI badges and/or MDI badges as part of a comprehensive isocyanates monitoring program. If allergy develops, very low future exposure can cause itching and a skin rash. DOW modified MDI products are made by reacting MDI with materials that have hydroxyl (-OH Data Sheet (SDS). contains diphenylmethane diisocyanate (cas no. What is Polymeric diphenylmethane diisocyanate (PMDI) and where is it found? Diphenylmethane diisocyanate (MDI) is the generic name of a product used in industrial settings. 04499600-. 02ppm MDI Prepolymer 53862-89-8 20-60 NO NDA NDA NDA Note: The dried film of this product may become a dust nuisance when removed by sanding or grinding. Material Safety Data Sheet) are interchangeable. Overall, the tumour incidence, Diphenylmethane 4,4'-diisocyanate (mixture of di-and triisocyanates) for synthesis. Its very low vapour pressure reduces its hazards during handling compared to the other major isocyanates (TDI, HDI). MDI, the second type of aromatic, comes in two forms: Pure MDI and polymeric MDI (PMDI). Sylvain Larose monomeric MDI also revealed an irritative effect with some pre-neoplastic changes in the highest exposure group. A Source Book and Practical Guide hazard ×exposure = risk The above expression cannot describe the diverse reactions of chemicals with humans and the environment, and is a great simplification of what are, almost SAFETY DATA SHEET. Jun 4, 2013 RUBINATE® ANd SUPRASEC® MdI SPECIAlTy ISoCyANATES 1 Polymeric MDI modified with a moderate level of 2,4' MDI isomer content. We have worldscale production facilities in the US, the Netherlands and China, and 30 highly capable downstream formulation facilities which are located close to our customers, worldwide. EPA defines hazardous waste in 40 CFR Part 261. . Page 5 of 9. Section 4 - First Aid Measures. , Ltd mainly products MDI-based Isocyanates, propylene oxide, polyether, acrylic acid and esters of petrochemical products. : name:hdi edition: wanhua chemical group co. BASF offers two standard monomeric MDI grades: pure 4,4’-MDI and a blend of 4,4’-MDI and 2,4’-MDI. H317. Use lukewarm water if possible. 1-2004, EU DIRECTIVE 91/155/EEC & 99/45/EC, OSHA 29 CFR 1910. 101-68-8). Acute (short-term) inhalation of high concentrations of MDI may cause sensitization and asthma in humans. Hazardous Component(s). MDI is sprayed, heated or used in a poorly ventilated area. ISO - MDI Page 3 of 7 FIRST AID MEASURES Ingestion: Never give fluids or induce vomiting if patient is unconcious or is having convulsions. SECTION 4: FIRST AID MEASURES Eye Contact: Can cause eye irritation. ECO-PROFILE OF MDI Table 1 shows the gross or cumulative energy to produce 1 kg of MDI and Table 2 gives this same data expressed in terms of primary fuels. H315. Greenberg, US Environmental Protection Agency 2 MDI and TDI: Safety, Health and the Environment. The Department of Labor does not endorse, takes no responsibility for, and exercises no control over the linked organization or its views, or contents, nor does it vouch for the accuracy or accessibility of the information contained on the destination server. MDI Prepolymer. Chemical Family: Aromatic Isocyanate. 652. Our (M)SDS database is an easy to use, do it yourself tool, and best of all it's free, paid for by our Covestro is a global leader in the development and manufacture of advanced materials. Routes of Exposure: Skin Contact: May cause skin irritation. It has a CASRN of 9016-87-9. Dermal. We also demonstrate our leadership through working towards improving health, safety and environment throughout the product life-cycle, from manufacture to customer to downstream user, in support of the ICCA Global Product Strategy. Risk factors. The substance identifiers displayed in the InfoCard are the best available substance name, EC number, CAS number and/or the molecular and structural formulas. Wanhua Chemical is the only Chinese manufacturer with MDI manufacturing technology based on our own intellectual property rights. SAFETY DATA SHEET Trade Name: ISO - ISOCYANATE - ISO COMPONENT A March 6, 2017 Shows that organic vapor cartridges without a particulate filter were not effective at removing Methylene bisphenyl isocyanate (MDI) aerosols from air, while organic vapor cartridges with dust/mist (DM) or high efficiency (HEPA) filters effectively removed greater than 99 percent of MDI aerosol and vapor in all test atmospheres. OSHA recommends a PEL/TWA of 15mg/m3 for total dust and 5mg/m3 for the respirable fraction. However, it, like the other isocyanates, is an allergen and sensitizer. MSDSonline – a VelocityEHS solution – is home to the industry leading online library of safety data sheets, or SDSs (formerly known as material safety data sheets, or MSDSs). Classified to the 2012 OSHA Hazard Communication Standard 29 CFR 1920. About 33% of these are polymer, 3% are syntheses material intermediates, and 1% are adhesives & sealants. Diphenylmethane diisocyanate (MDI) is the generic name of a product used in industrial settings. MSDS Date:08/17/1990. The main application for Polymeric MDI is in the Polyurethanes industry: Construction Panels, Spray Heat Insulation, Refrigerators and Car Interiors. Methylenediphenyl Diisocyanate. Causes skin irritation. MATERIAL SAFETY DATA SHEET Page 2 of 9 Rust Preventive Paint Part No. 25 g/mol. Basis for original (SCP) IDLH: The chosen IDLH is based on an analogy with toluene diisocyanate, which has an IDLH of 10 ppm. BASF offers a comprehensive polyurethanes product portfolio from basic products (polyether polyols, polyester polyols, MDI and TDI) to polyurethane systems and speciality elastomers (thermoplastic polyurethane – TPU and microcellular elastomers as a finished product). Hazardous waste regulations are developed and implemented by the U. For more information, please refer to our MSDS or contact our customer service center. Organic compounds that contain an isocyanate group are referred to as isocyanates. The composition of the reaction product depends on the ratios of the starting materials and on the reaction conditions. risk, hazard and MSDS, CAS,cas number,Use,cas no may also be you need. overexposure well above the pel may result in bronchitis, bronchial spasms and pulmonary edema. Sekizawa, National Institute of Health Sciences, Japan, in collaboration with Dr M. Rats have been exposed for two years to a respirable aerosol of polymeric MDI top level (6 mg/m3), there was a significant incidence of a benign tumour of the lung (adenoma) and one malignant tumour (adenocarcinoma). Use fingers to ensure that eyelids are separated and that the eye is being irrigated. It may be toxic by ingestion, inhalation, or skin absorption. At this point, please call MDI Inc. In such cases, or whenever concentrations of MDI exceed the TLV or are not known, respiratory protection must be worn. Solid at room temperature. A supplied air respirator (either positive pressure or continuous flow type) is required. Conditions to Avoid: High temperatures, dust generation, moisture, At room temperature, MDI Explore information about Air pollutants, contaminants and studies being done New Advances in Polymeric MDI Variants Thorsten Gurke Application and Product Development Manager - Adhesives Huntsman Polyurethanes Everslaan 45 B3078 Everberg, Belgium Tel. , Mississauga, Ontario, L5N 2L7, Canada TDI is used primarily in the production of flexible foams. O. Polymeric MDI is a brown liquid. Whether you need off-the-shelf chemicals for R&D or customized, fit-for-use raw materials for manufacturing applications, we are your ideal medical materials partner. Revision: 01/08/2017 Page: 2 of 5 Salbutamol SAFETY DATA SHEET 2. MDI exposure can affect skin, eyes, and lungs. P, for special handling instructions. Substance identity Substance identity. Trade Secret*. There were no lung tumours at 1 mg/m3 and no effects at 0. A used relay could release mercury. Oct 29, 2014 This product safety assessment covers a group of products that share similar characteristics and properties. Polymeric MDI (PMDI), the primary technical/commercial form of MDI, is actually a mixture that contains 25–80% monomeric 4,4’-MDI as well as oligomers containing 3–6 rings and other minor isomers, such as the 2,2’-isomer. First aid measures Eye contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. mixture containing unreacted MDI. ROYALCAST® TDI- and MDI-based Prepolymers for applications that require higher hardness to 85D including sub-sea pipe protection, cable protection and bowling balls. Acute. Three isomers are common, varying by the positions of the  Aug 21, 2015 DOW™ Modified Methyl Diphenyl Diisocyanate (MDI) Products. MSDS incomplete, inaccurate or We use cookies and tracking technologies to offer you a better browsing experience, analyze site traffic, and improve the website. MDI offers a complete retail wholesale operation supplying over 650 stores in the US and overseas. This mixture is often known as polymeric MDA. NIIN:00N019876. NO. MDI, methylene diphenyl diisocyanate, CAS: 101-68-8, is one of the most important chemical raw materials currently used in the polyurethane industry. Strong/MDI is a proactive collaborator, they have been involved in the screen and structure design of many of our products and major projects, including our award winning Multimedia based Interactive Dark ride. > 97 Trade Secret *. By clicking “Accept Cookies”, you expressly agree to our use of cookies and tracking technologies in accordance with our Cookie Policy. 1200, NOHSC:2011(2003), AND CANADIAN CPR (MDI) 101-68-8 1 - 5% Diphenylmethane Diisocyanate (MDI) Mixed Isomers 26447-40-5 4. For information about a specific  The commercial form of 4,4'-methylenediphenyl diisocyanate (MDI) is used to produce polyurethane Chronic (long-term) inhalation exposure to MDI has been. Dow provides health, safety and environmental information to our direct product receivers through documents called Safety Data Sheets (SDS) and product labels. It is not soluble in water. CAS Number. P. Synonyms: MDI;MBI;Isonate;4,4'-MDI;DESMODUR;hylenem50;methylene  Product Identifier: Unfinished MDI bonded, formaldehyde free, moisture resistant Methylene-diphenyl-diisocyanate (MDI)4 Ingredients section of this MSDS. e. Besides the standard MMDIs, various MMDI Monomeric MDI Carbodiimide Modified MDI types with different stabilization and reactivity are available. Bunge W, Ehrlicher H, Kimmerle G [1977]. Diphenylmethane Diisocyanate  Mechanical Property Data Dow PAPI™ 20 Polymeric MDI, Dow PAPI™ 27 Polymeric MDI, Dow PAPI™ 580 N Polymeric MDI, Dow PAPI™ 901 Polymeric MDI,  WANNATE MDI-100 is pure MDI containing at least 98% 4, . 15 mg/kg. HAZARD STATEMENTS. === Responsible Party ===. An organic compound with two isocyanate groups is known as a diisocyanate. TDI and MDI are extremely reactive chemicals and are not likely to stay in the environment. MDI is the standard abbreviation for methylene diphenyl diisocyanate. It is solvent-free form with 2. In 2008, the U. Isocyanate is the functional group with the formula R–N=C=O. Company. 278 MDI and TDI: Safety, Health and the Environment. In case of eye contact, hold eyes open and IMMEDIATELY, rinse thoroughly with plenty of water. Environmental Protection Agency (EPA) as directed by Congress in the Resource Conservation and Recovery Act of 1976 (RCRA). for specific hazardous material handling. Particle board, a big part of new-home construction, is manufactured using adhesives from MDI. Table 6 shows the gross Millionate® MR/MT : Millionate MT [Monomeric MDI] Millionate MT is an aromatic diisocyanate having two isocyanate groups of equal reactivity. 12 East Edwardsburg, Michigan 49112. 메틸렌 디페닐 디이소시아네이트(MDI, Methylene Diphenyl Diisocyanate)는 방향족 디이소시아네이트류 화학 물질이다. TDI and MDI rapidly react with water to form other compounds in a process called hydrolysis. Prolonged or repeated contact may cause skin irritation and may stain the skin. Section 7: Handling and Storage Handling: Do not breathe fumes, vapors or spray mist from this material. MDI and other isocyanates may also cause hypersensitivity pneumonitis, another allergic lung disease, which is characterized by symptoms such as shortness of breath, fever, tiredness, non- productive cough, and chills. Huntsman Polyurethanes is a global leader in MDI-based polyurethanes, serving over 3,000 customers in more than 90 countries. Skin Irritation, category 2. MDI is commonly used in the production of adhesives, automobile bumpers, shoe soles, coated fabrics and spandex fibers. It is used to make plastics. Close to the markets with world-scale plants. Contact with the skin, eyes, and mucous membranes may result in severe irritation and permanent damage. Pure MDI is a solid at room temperature with a melting point of 38°C. Table 3 shows the energy data expressed as masses of fuels. PRODUCT NAME: 2 Part  Mar 25, 2015 An MDI study has demonstrated that a poly glycol-based skin cleanser (such as D-TamTM, PEG-400) or corn oil may be more effective than  Non-isomer specific CAS number includes 2,2' MDI and 2,4' MDI. It may be toxic by ingestion, inhalation, or skin absorption. 4,4' Diphenylmethane Diisocyanate (MDI) 101-68-8. It is soluble in acetone, benzene, kerosene, and nitrobenzene (monomer). It exists in three isomers, 2,2'-MDI, 2,4'-MDI, and 4,4'-MDI, however, the 4,4' isomer is most widely used. It is soluble in acetone, benzene, kerosene, and nitrobenzene  101-68-8; EC Number: 202-966-0; Synonym: 4,4′-MDI, Bis(4- isocyanatophenyl)methane; Linear Formula: C15H10N2O2; find Sigma-Aldrich- 256439 MSDS,  DIPHENYLMETHANE-DIISOCYANATE (MDI). We value their ongoing support and their dynamic approach to helping us find practical solutions. In the United States, MDI is the standard abbreviation for “pure” diphenylmethane diisocyanate. P,P'-DIPHENYLMETHANE DIISOCYANATE (MDI) 101-68-8. Consequently, Millionate MT is suitable for the preparation of liner polymers by reaction with diols and diamines. 404. In the European Union the term Safety data sheet may be used. “MDI” refers to a mixture of 4,4’-methylenediphenyl diisocyanate and its isomers. Mercury is very hazardous and must be handled properly. Wanhua Chemical Group Co. MSDS Number: BNVGP. MDI is used in the manufacturing of rigid foams, and when heated causes asthma-like conditions when inhaled as an aerosol. AS ATTACHED. Lupranat MI 33,5 12 25 Blend of monomeric 4,4’-MDI and 2,4’-MDI isomers. It is not soluble in water. An MDI Spill Kit (MDI Part# SP-1149) is available for purchase upon request. This makes MDI somewhat less hazardous than TDI, so it has been replacing TDI in certain applications. Skin Absorption: May be harmful if absorbed  May 21, 2015 MSDS Request. Business  May 23, 2014 Chemical Name: Diphenylmethane Diisocyanate (MDI). Box 710 25028 U. • In air, TDI and MDI have half-lives (amount of time needed for the amount of TDI or MDI in air to be reduced by one-half) of less than 1 day Methylene diphenyl diisocyanate (MDI) is a light yellow solid and is an aromatic diisocyanate. M. ISOCYANATE (MDI)™ Synergy Series (A) SDS-314. 6 Polyurethane Basic Products – Isocyanates and polyols for versatile polymers Product NCO content [%] Viscosity [mPa*s] Viscosity Temperature [°C] Description Lupranat ME 33,5 5 42 Pure monomeric 4,4’-MDI. * Methylene Bisphenyl Isocyanate may cause an asthma-like allergy. com offers 137 mdi diphenylmethane diisocyanate products. SAFETY DATA SHEET Product Name: Base Seal® (Component ‘A’, Isocyanate) MSDS A-004 Page 1 of 9 6747 Campobello Rd. been classified according to the hazard criteria of the CPR and the MSDS contains  Product ID:RUBINATE M (POLYMERIC MDI). 1 Revision 3 ˜ September 30, 2011 CONFORMS TO THE GLOBALLY HARMONIZED SYSTEM (GHS), ANSI Z400. Provide adequate ventilation in the workplace. POLYURETHANE RESIN (NJTS REG. 1200. MDI is mainly used for bonding rubber to nylon and other adhesives. Safety data sheet ELASTOPOR P1046U ISOCYANATE (CYL) Inhalation of MDI vapors may cause irritation of the mucous membranes of the nose, throat or Safety data Methylene Bisphenyl Isocyanate has not been tested for its ability to affect reproduction. The type of protection selected must comply with the requirements set Explore information about Air pollutants, contaminants and studies being done Airborne MDI concentrations greater than the ACGIH TLV-TWA(TWA) or OSHA PEL-C(PEL) can occur in inadequately ventilated environments when MDI is sprayed, aerosolized or heated. Material may be irritating to the mucous membranes and upper respiratory tract. exposure. Product Safety As used herein, the terms SDS and MSDS (i. COMPONENT MATERIALS HEALTH RISKS. Material Safety. If Polymeric MDI is released, leave the area until the severity of the release is Signs and Symptoms of Acute Methyl Isocyanate Exposure: Acute exposure to methyl isocyanate may result in respiratory tract irritation, cough, chest tightness and pain, dyspnea (shortness of breath), asthmatic episodes, and pulmonary edema. Effects on the reproductive system Not available Teratogenic effects Not available Others Not available 12. , ltd section 1-chemical product and company identification Product name: MILLIONATE MR-200 1986/11/05 6 Mutagenic effects (For 4,4’-MDI) This product contains over 1% of 4,4’-MDI, which showed a mutagenic effect to a certain salmonella (TA-98, TA-100), when S-9Mix was added in Ames test. Recruitment People for the Kumho Petrochemical Group who will continuously challenge and lead in the global markets, as they are not content with glorifying their past achievements MDI understands the importance of creating order quickly and decisively for traffic incident management or other emergency situations. The unit(s) MUST be placed in a separate sealed container (plastic bucket with lid, or can with lid). MSDSonline’s millions of safety sheets contain the information you need to keep your business or organization safe from dangerous chemicals such as methanol, acetone Also consult the applicable MSDS sheet. FSC:8040. In an emergency situation, a self-contained breathing apparatus may be used. Ingestion: This is not considered a common occupation route of exposure, and single dose toxicity is low. COSMONATE M-200 is polymeric MDI, generally used in manufacturing hard and semi-hard polyurethane foam. Skin: May cause allergic skin reaction in susceptible individuals. MDI is the least hazardous of the commonly available isocyanates but is not benign. An animal study indicates that MDI may induce hypersensitivity following dermal exposure. 1 Description of first aid measures. Because MDI is a dangerous threat if inhaled, the chemical is ジフェニルメタンジイソシアネートは、通常mdiと略され、芳香族 ジイソシアネートのひとつである。mdiには、2,2'-mdi, 2,4'-mdi及び4,4'-mdiの3種類の異性体が存在している。 MDI Products MDI offers 50,000 items across ambient, refrigerated, and frozen climate zones, with deep assortments in all product categories. ORIGINAL MSDS FROM MANUFACTURER. ] 1. 2 mg/m3. *Please select more than one item to compare 4,4'-Methylenediphenyl Diisocyanate (MDI) 101-68-8 Hazard Summary The commercial form of 4,4'-methylenediphenyl diisocyanate (MDI) is used to produce polyurethane foams. In such cases, respiratory protection must be worn. •DI and MDI can be released into the air, water, and soil T at places where they are produced or used. +32 2 758 9298 [email protected] - Find MSDS or SDS, a COA, data sheets and more information. Odor: Slightly musty. Avoid contact with skin and eyes. long-term exposure to isocyanates has Search results for MDI at Sigma-Aldrich. COSMONATE M-200 is liquefied in normal temperature and easily handled and stored down to -20℃. The ‘Substance identity’ section is calculated from substance identification information from all ECHA databases. Airborne MDI concentrations greater than the ACGIH TLV-TWA(TWA) or OSHA PEL-C(PEL) can occur in inadequately ventilated environments when MDI is sprayed, aerosolized or heated. mdi msds

y9, os, aa, tk, gr, rx, pg, xz, it, jn, y3, e5, al, na, oq, hl, pg, ab, 0t, 9r, 9g, cd, gt, bn, ut, pz, ob, jh, 9g, oz, i8,